change shutter to 300(photogeeks will shreek but the inverse thing is not applied until it starts proccessing the render),keep iso at 100, turn off vignette, change f-number to 8, drag vraysky from enviro dialog(press the 8 key) to enviro override in render dialog and also to a slot in material editor to make sure that it not set to manual sun node, make sure size and intensity of sun is set to 1.0, change GI bounce to 1, on Irradiance map if high takes to long set to medium(I have notice little difference with well modeled geometry) and check show calc phase, try light cache for secondary and make sure show calc phase is checked(this will provide a preview of how well the scene is lit), for color mapping I would use reinhard with gamma set to 1.2(it weakens the shadow darkness). i hope the render dialog image was just to show your settings. you need to render the camera view and more importantly the vray camera view for this to work. has the render time improved. run tests previews at low res and once you get that right setting render at high res.